This is “Essential Skills 6”, section 11.9 from the book Principles of General Chemistry (v. 1.0).
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Essential Skills 3 in Chapter 4 "Reactions in Aqueous Solution", Section 4.10 "Essential Skills 3", introduced the common, or base-10, logarithms and showed how to use the properties of exponents to perform logarithmic calculations. In this section, we describe natural logarithms, their relationship to common logarithms, and how to do calculations with them using the same properties of exponents.
Many natural phenomena exhibit an exponential rate of increase or decrease. Population growth is an example of an exponential rate of increase, whereas a runner’s performance may show an exponential decline if initial improvements are substantially greater than those that occur at later stages of training. Exponential changes are represented logarithmically by e^{x}, where e is an irrational number whose value is approximately 2.7183. The natural logarithm, abbreviated as ln, is the power x to which e must be raised to obtain a particular number. The natural logarithm of e is 1 (ln e = 1).
Some important relationships between base-10 logarithms and natural logarithms are as follows:
10^{1} = 10 = e^{2.303} ln e^{x} = x ln 10 = ln(e^{2.303}) = 2.303 log 10 = ln e = 1According to these relationships, ln 10 = 2.303 and log 10 = 1. Because multiplying by 1 does not change an equality,
ln 10 = 2.303 log 10Substituting any value y for 10 gives
ln y = 2.303 log yOther important relationships are as follows:
log A^{x} = x log A ln e^{x} = x ln e = x = e^{ln} ^{x}Entering a value x, such as 3.86, into your calculator and pressing the “ln” key gives the value of ln x, which is 1.35 for x = 3.86. Conversely, entering the value 1.35 and pressing “e^{x}” key gives an answer of 3.86.On some calculators, pressing [INV] and then [ln x] is equivalent to pressing [ex]. Hence
e^{ln3.86} = e^{1.35} = 3.86 ln(e^{3.86}) = 3.86Calculate the natural logarithm of each number and express each as a power of the base e.
Solution:
What number is each value the natural logarithm of?
Solution:
Like common logarithms, natural logarithms use the properties of exponents. We can expand Table 4.5 "Relationships in Base-10 Logarithms" in Essential Skills 3 to include natural logarithms:
Operation | Exponential Form | Logarithm |
---|---|---|
Multiplication | (10^{a})(10^{b}) = 10^{a} ^{+} ^{b} | log(ab) = log a + log b |
(e^{x})(e^{y}) = e^{x} ^{+} ^{y} | ln(e^{x}e^{y}) = ln(e^{x}) + ln(e^{y}) = x + y | |
Division | $\begin{array}{c}\frac{{10}^{a}}{{10}^{b}}={10}^{a\text{}-\text{}b}\\ \frac{{e}^{x}}{{e}^{y}}={e}^{x\text{}-\text{}y}\end{array}$ | $\begin{array}{c}\mathrm{log}\left(\frac{a}{b}\right)=\mathrm{log}\text{}a-\mathrm{log}\text{}b\\ \text{ln}\left(\frac{x}{y}\right)=\text{ln}x-\text{ln}y\\ \mathrm{ln}\left(\frac{{e}^{x}}{{e}^{y}}\right)=\mathrm{ln}({e}^{x})-\mathrm{ln}({e}^{y})=x-y\end{array}$ |
Inverse | $\begin{array}{c}\mathrm{log}\left(\frac{1}{a}\right)=-\mathrm{log}a\\ \mathrm{ln}\left(\frac{1}{x}\right)=-\text{ln}x\end{array}$ |
The number of significant figures in a number is the same as the number of digits after the decimal point in its logarithm. For example, the natural logarithm of 18.45 is 2.9151, which means that e^{2.9151} is equal to 18.45.
Calculate the natural logarithm of each number.
Solution:
The answers obtained using the two methods may differ slightly due to rounding errors.
Calculate the natural logarithm of each number.
Solution: