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9.1 Solutions

Learning Objective

  1. Understand what causes solutions to form.

A solutionAnother name for a homogeneous mixture. is another name for a homogeneous mixture. Chapter 1 "Chemistry, Matter, and Measurement" defined a mixture as a material composed of two or more substances. In a solution, the combination is so intimate that the different substances cannot be differentiated by sight, even with a microscope. Compare, for example, a mixture of salt and pepper and another mixture consisting of salt and water. In the first mixture, we can readily see individual grains of salt and the flecks of pepper. A mixture of salt and pepper is not a solution. However, in the second mixture, no matter how carefully we look, we cannot see two different substances. Salt dissolved in water is a solution.

The major component of a solution, called the solventThe major component of a solution., is typically the same phase as the solution itself. Each minor component of a solution (and there may be more than one) is called the soluteThe minor component of a solution.. In most of the solutions we will describe in this textbook, there will be no ambiguity about whether a component is the solvent or the solute.) For example, in a solution of salt in water, the solute is salt, and solvent is water.

Solutions come in all phases, and the solvent and the solute do not have to be in the same phase to form a solution (such as salt and water). For example, air is a gaseous solution of about 80% nitrogen and about 20% oxygen, with some other gases present in much smaller amounts. An alloyA solid solution of a metal with other substances dissolved in it. is a solid solution consisting of a metal (like iron) with some other metals or nonmetals dissolved in it. Steel, an alloy of iron and carbon and small amounts of other metals, is an example of a solid solution. Table 9.1 "Types of Solutions" lists some common types of solutions, with examples of each.

Table 9.1 Types of Solutions

Solvent Phase Solute Phase Example
gas gas air
liquid gas carbonated beverages
liquid liquid ethanol (C2H5OH) in H2O (alcoholic beverages)
liquid solid saltwater
solid gas H2 gas absorbed by Pd metal
solid liquid Hg(ℓ) in dental fillings
solid solid steel alloys

What causes a solution to form? The simple answer is that the solvent and the solute must have similar intermolecular interactions. When this is the case, the individual particles of solvent and solute can easily mix so intimately that each particle of solute is surrounded by particles of solute, forming a solution. However, if two substances have very different intermolecular interactions, large amounts of energy are required to force their individual particles to mix intimately, so a solution does not form.

This process leads to a simple rule of thumb: like dissolves like. Solvents that are very polar will dissolve solutes that are very polar or even ionic. Solvents that are nonpolar will dissolve nonpolar solutes. Thus water, being polar, is a good solvent for ionic compounds and polar solutes like ethanol (C2H5OH). However, water does not dissolve nonpolar solutes, such as many oils and greases (Figure 9.1 "Solubility").

Figure 9.1 Solubility

Because of different intermolecular interactions, oil (on top) and water (bottom, colored red) do not dissolve in each other.

We use the word solubleA solute that dissolves in a particular solvent. to describe a solute that dissolves in a particular solvent, and the word insolubleA solute that does not dissolve in a particular solvent. for a solute that does not dissolve in a solvent. Thus, we say that sodium chloride is soluble in water but insoluble in hexane (C6H14). If the solute and the solvent are both liquids and soluble in any proportion, we use the word miscibleLiquids that dissolve in each other., and the word immiscibleLiquids that do not dissolve in each other. if they are not.

Example 1

Water is considered a polar solvent. Which substances should dissolve in water?

  1. methanol (CH3OH)
  2. sodium sulfate (Na2SO4)
  3. octane (C8H18)

Solution

Because water is polar, substances that are polar or ionic will dissolve in it.

  1. Because of the OH group in methanol, we expect its molecules to be polar. Thus, we expect it to be soluble in water. As both water and methanol are liquids, the word miscible can be used in place of soluble.
  2. Sodium sulfate is an ionic compound, so we expect it to be soluble in water.
  3. Like other hydrocarbons, octane is nonpolar, so we expect that it would not be soluble in water.

Skill-Building Exercise

    Toluene (C6H5CH3) is widely used in industry as a nonpolar solvent. Which substances should dissolve in toluene?

  1. water (H2O)

  2. sodium sulfate (Na2SO4)

  3. octane (C8H18)

Concept Review Exercises

  1. What causes a solution to form?

  2. How does the phrase like dissolves like relate to solutions?

Answers

  1. Solutions form because a solute and a solvent have similar intermolecular interactions.

  2. It means that substances with similar intermolecular interactions will dissolve in each other.

Key Takeaway

  • Solutions form because a solute and a solvent experience similar intermolecular interactions.

Exercises

  1. Define solution.

  2. Give several examples of solutions.

  3. What is the difference between a solvent and a solute?

  4. Can a solution have more than one solute in it? Can you give an example?

  5. Does a solution have to be a liquid? Give several examples to support your answer.

  6. Give at least two examples of solutions found in the human body.

  7. Which substances will probably be soluble in water, a very polar solvent?

    1. sodium nitrate (NaNO3)
    2. hexane (C6H14)
    3. isopropyl alcohol [(CH3)2CHOH]
    4. benzene (C6H6)
  8. Which substances will probably be soluble in toluene (C6H5CH3), a nonpolar solvent?

    1. sodium nitrate (NaNO3)
    2. hexane (C6H14)
    3. isopropyl alcohol [(CH3)2CHOH]
    4. benzene (C6H6)
  9. The solubility of alcohols in water varies with the length of carbon chain. For example, ethanol (CH3CH2OH) is soluble in water in any ratio, while only 0.0008 mL of heptanol (CH3CH2CH2CH2CH2CH2CH2OH) will dissolve in 100 mL of water. Propose an explanation for this behavior.

  10. Dimethyl sulfoxide [(CH3)2SO] is a polar liquid. Based on the information in Exercise 9, which do you think will be more soluble in it—ethanol or heptanol?

Answers

  1. a homogeneous mixture

  2. A solvent is the majority component of a solution; a solute is the minority component of a solution.

  3. A solution does not have to be liquid; air is a gaseous solution, while some alloys are solid solutions (answers will vary).

    1. probably soluble
    2. probably not soluble
    3. probably soluble
    4. probably not soluble
  4. Small alcohol molecules have strong polar intermolecular interactions, so they dissolve in water. In large alcohol molecules, the nonpolar end overwhelms the polar end, so they do not dissolve very well in water.