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3.2 Molecules and Chemical Nomenclature

Learning Objectives

  1. Define molecule.
  2. Name simple molecules based on their formulas.
  3. Determine a formula of a molecule based on its name.

There are many substances that exist as two or more atoms connected together so strongly that they behave as a single particle. These multiatom combinations are called moleculesThe smallest part of a substance that has the physical and chemical properties of that substance.. A molecule is the smallest part of a substance that has the physical and chemical properties of that substance. In some respects, a molecule is similar to an atom. A molecule, however, is composed of more than one atom.

Some elements exist naturally as molecules. For example, hydrogen and oxygen exist as two-atom molecules. Other elements also exist naturally as diatomic moleculesA molecule with only two atoms. (see Table 3.3 "Elements That Exist as Diatomic Molecules"). As with any molecule, these elements are labeled with a molecular formulaA formal listing of what and how many atoms are in a molecule., a formal listing of what and how many atoms are in a molecule. (Sometimes only the word formula is used, and its meaning is inferred from the context.) For example, the molecular formula for elemental hydrogen is H2, with H being the symbol for hydrogen and the subscript 2 implying that there are two atoms of this element in the molecule. Other diatomic elements have similar formulas: O2, N2, and so forth. Other elements exist as molecules—for example, sulfur normally exists as an eight-atom molecule, S8, while phosphorus exists as a four-atom molecule, P4 (see Figure 3.3 "Molecular Art of S"). Otherwise, we will assume that elements exist as individual atoms, rather than molecules. It is assumed that there is only one atom in a formula if there is no numerical subscript on the right side of an element’s symbol.

Table 3.3 Elements That Exist as Diatomic Molecules

Hydrogen
Oxygen
Nitrogen
Fluorine
Chlorine
Bromine
Iodine

Figure 3.3 Molecular Art of S8 and P4 Molecules

If each green ball represents a sulfur atom, then the diagram on the left represents an S8 molecule. The molecule on the right shows that one form of elemental phosphorus exists, as a four-atom molecule.

Figure 3.3 "Molecular Art of S" shows two examples of how we will be representing molecules in this text. An atom is represented by a small ball or sphere, which generally indicates where the nucleus is in the molecule. A cylindrical line connecting the balls represents the connection between the atoms that make this collection of atoms a molecule. This connection is called a chemical bondThe connection between two atoms in a molecule.. In Chapter 9 "Chemical Bonds", we will explore the origin of chemical bonds. You will see other examples of this “ball and cylinder” representation of molecules throughout this book.

Many compounds exist as molecules. In particular, when nonmetals connect with other nonmetals, the compound typically exists as molecules. (Compounds between a metal and a nonmetal are different and will be considered in Section 3.4 "Ions and Ionic Compounds".) Furthermore, in some cases there are many different kinds of molecules that can be formed between any given elements, with all the different molecules having different chemical and physical properties. How do we tell them apart?

The answer is a very specific system of naming compounds, called chemical nomenclatureA very specific system for naming compounds, in which unique substances get unique names.. By following the rules of nomenclature, each and every compound has its own unique name, and each name refers to one and only one compound. Here, we will start with relatively simple molecules that have only two elements in them, the so-called binary compounds:

  1. Identify the elements in the molecule from its formula. This is why you need to know the names and symbols of the elements in Table 3.2 "Names and Symbols of Common Elements".
  2. Begin the name with the element name of the first element. If there is more than one atom of this element in the molecular formula, use a numerical prefix to indicate the number of atoms, as listed in Table 3.4 "Numerical Prefixes Used in Naming Molecular Compounds". Do not use the prefix mono- if there is only one atom of the first element.

    Table 3.4 Numerical Prefixes Used in Naming Molecular Compounds

    The Number of Atoms of an Element Prefix
    1 mono-
    2 di-
    3 tri-
    4 tetra-
    5 penta-
    6 hexa-
    7 hepta-
    8 octa-
    9 nona-
    10 deca-
  3. Name the second element by using three pieces:

    1. a numerical prefix indicating the number of atoms of the second element, plus
    2. the stem of the element name (e.g., ox for oxygen, chlor for chlorine, etc.), plus
    3. the suffix -ide.
  4. Combine the two words, leaving a space between them.

Let us see how these steps work for a molecule whose molecular formula is SO2, which has one sulfur atom and two oxygen atoms—this completes step 1. According to step 2, we start with the name of the first element—sulfur. Remember, we don’t use the mono- prefix for the first element. Now for step 3, we combine the numerical prefix di- (see Table 3.4 "Numerical Prefixes Used in Naming Molecular Compounds") with the stem ox- and the suffix -ide, to make dioxide. Bringing these two words together, we have the unique name for this compound—sulfur dioxide.

Why all this trouble? There is another common compound consisting of sulfur and oxygen whose molecular formula is SO3, so the compounds need to be distinguished. SO3 has three oxygen atoms in it, so it is a different compound with different chemical and physical properties. The system of chemical nomenclature is designed to give this compound its own unique name. Its name, if you go through all the steps, is sulfur trioxide. Different compounds have different names.

In some cases, when a prefix ends in a or o and the element name begins with o we drop the a or o on the prefix. So we see monoxide or pentoxide rather than monooxide or pentaoxide in molecule names.

One great thing about this system is that it works both ways. From the name of a compound, you should be able to determine its molecular formula. Simply list the element symbols, with a numerical subscript if there is more than one atom of that element, in the order of the name (we do not use a subscript 1 if there is only one atom of the element present; 1 is implied). From the name nitrogen trichloride, you should be able to get NCl3 as the formula for this molecule. From the name diphosphorus pentoxide, you should be able to get the formula P2O5 (note the numerical prefix on the first element, indicating there is more than one atom of phosphorus in the formula).

Example 3

Name each molecule.

  1. PF3
  2. CO
  3. Se2Br2

Solution

  1. A molecule with a single phosphorus atom and three fluorine atoms is called phosphorus trifluoride.
  2. A compound with one carbon atom and one oxygen atom is properly called carbon monoxide, not carbon monooxide.
  3. There are two atoms of each element, selenium and bromine. According to the rules, the proper name here is diselenium dibromide.

Test Yourself

Name each molecule.

  1. SF4
  2. P2S5

Answers

  1. sulfur tetrafluoride
  2. diphosphorus pentasulfide

Example 4

Give the formula for each molecule.

  1. carbon tetrachloride
  2. silicon dioxide
  3. trisilicon tetranitride

Solution

  1. The name carbon tetrachloride implies one carbon atom and four chlorine atoms, so the formula is CCl4.
  2. The name silicon dioxide implies one silicon atom and two oxygen atoms, so the formula is SiO2.
  3. We have a name that has numerical prefixes on both elements. Tri- means three, and tetra- means four, so the formula of this compound is Si3N4.

Test Yourself

Give the formula for each molecule.

  1. disulfur difluoride
  2. iodine pentabromide

Answers

  1. S2F2
  2. IBr5

Some simple molecules have common names that we use as part of the formal system of chemical nomenclature. For example, H2O is given the name water, not dihydrogen monoxide. NH3 is called ammonia, while CH4 is called methane. We will occasionally see other molecules that have common names; we will point them out as they occur.

Key Takeaways

  • Molecules are groups of atoms that behave as a single unit.
  • Some elements exist as molecules: hydrogen, oxygen, sulfur, and so forth.
  • There are rules that can express a unique name for any given molecule, and a unique formula for any given name.

Exercises

  1. Which of these formulas represent molecules? State how many atoms are in each molecule.

    1. Fe
    2. PCl3
    3. P4
    4. Ar
  2. Which of these formulas represent molecules? State how many atoms are in each molecule.

    1. I2
    2. He
    3. H2O
    4. Al
  3. What is the difference between CO and Co?

  4. What is the difference between H2O and H2O2 (hydrogen peroxide)?

  5. Give the proper formula for each diatomic element.

  6. In 1986, when Halley’s comet last passed the earth, astronomers detected the presence of S2 in their telescopes. Why is sulfur not considered a diatomic element?

  7. What is the stem of fluorine used in molecule names? CF4 is one example.

  8. What is the stem of selenium used in molecule names? SiSe2 is an example.

  9. Give the proper name for each molecule.

    1. PF3
    2. TeCl2
    3. N2O3
  10. Give the proper name for each molecule.

    1. NO
    2. CS2
    3. As2O3
  11. Give the proper name for each molecule.

    1. XeF2
    2. O2F2
    3. SF6
  12. Give the proper name for each molecule.

    1. P4O10
    2. B2O3
    3. P2S3
  13. Give the proper name for each molecule.

    1. N2O
    2. N2O4
    3. N2O5
  14. Give the proper name for each molecule.

    1. SeO2
    2. Cl2O
    3. XeF6
  15. Give the proper formula for each name.

    1. dinitrogen pentoxide
    2. tetraboron tricarbide
    3. phosphorus pentachloride
  16. Give the proper formula for each name.

    1. nitrogen triiodide
    2. diarsenic trisulfide
    3. iodine trichloride
  17. Give the proper formula for each name.

    1. dioxygen dichloride
    2. dinitrogen trisulfide
    3. xenon tetrafluoride
  18. Give the proper formula for each name.

    1. chlorine dioxide
    2. selenium dibromide
    3. dinitrogen trioxide
  19. Give the proper formula for each name.

    1. iodine trifluoride
    2. xenon trioxide
    3. disulfur decafluoride
  20. Give the proper formula for each name.

    1. germanium dioxide
    2. carbon disulfide
    3. diselenium dibromide

Answers

    1. not a molecule
    2. a molecule; four atoms total
    3. a molecule; four atoms total
    4. not a molecule
  1. CO is a compound of carbon and oxygen; Co is the element cobalt.

  2. H2, O2, N2, F2, Cl2, Br2, I2

  3. fluor-

    1. phosphorus trifluoride
    2. tellurium dichloride
    3. dinitrogen trioxide
    1. xenon difluoride
    2. dioxygen difluoride
    3. sulfur hexafluoride
    1. dinitrogen monoxide
    2. dinitrogen tetroxide
    3. dinitrogen pentoxide
    1. N2O5
    2. B4C3
    3. PCl5
    1. O2Cl2
    2. N2S3
    3. XeF4
    1. IF3
    2. XeO3
    3. S2F10